Volume 4 Issue 2
Jun.  2011
Turn off MathJax
Article Contents
Ni SU, Jin-zhou DU, Tao JI, Jing ZHANG. 2011: 226Ra and 228Ra tracer study on material transport in the east coast of Hainan Island, China: a case of nutrients. Water Science and Engineering, 4(2): 157-169. doi: 10.3882/j.issn.1674-2370.2011.02.004
Citation: Ni SU, Jin-zhou DU, Tao JI, Jing ZHANG. 2011: 226Ra and 228Ra tracer study on material transport in the east coast of Hainan Island, China: a case of nutrients. Water Science and Engineering, 4(2): 157-169. doi: 10.3882/j.issn.1674-2370.2011.02.004

226Ra and 228Ra tracer study on material transport in the east coast of Hainan Island, China: a case of nutrients

doi: 10.3882/j.issn.1674-2370.2011.02.004
Funds:  Major Science and Technology Program for Water Pollution Control and Treatment in China;Major Science and Technology Program for Water Pollution Control and Treatment in China
  • Received Date: 2010-08-14
  • Rev Recd Date: 2011-05-02
  • Material fluxes (e.g. nutrients) from coast to offshore play an important role in controlling the water quality in the concerned adjacent sea not only by the increase of nutrient concentration but by the change of nutrient structure. In the present work, naturally occurring isotopes (226Ra and 228Ra) had been measured by alpha spectrometry in Wenjiao/Wenchang and Wanquan river estuaries and adjacent sea water of the east coast of Hainan Island. The excess dissolved 226Ra and 228Ra activities were observed in comparison with the values expected from the conservative mixing of freshwater and seawater end-members in both estuaries. Using 1-Dimensional Diffusion model, the estimated horizontal eddy diffusion coefficients (Kh) derived from 228Ra activities away from its sources was 3.16?105 cm2 s-1. Furthermore, the corresponding nutrient fluxes into the coastal area were assessed. The results can provide useful information for the processes of mixing and exchange of coastal water as well as the transportation of dissoluble pollutants in this sea area.

     

  • loading
  • Beck, A. J., Rapaglia, J. P., Cochran, J. K., and Bokuniewicz, H. J. 2007. Radium mass-balance in Jamaica Bay, NY: Evidence for a substantial flux of submarine groundwater. Marine Chemistry, 106(3-4), 419-441. [doi: 10.1016/j.marchem.2007.03.008]
    Burnett, W. C., Cowart, J. B., and Deetae, S. 1990. Radium in the Suwannee River and Estuary: Spring and river input to the Gulf of Mexico. Biogeochemistry, 10(3), 237-255. [doi: 10.1007/BF00003146]
    Charette, M. A. 2007. Hydrologic forcing of submarine groundwater discharge: Insight from a seasonal study of radium isotopes in a groundwater-dominated salt marsh estuary. Limnology and Oceanogaphy, 52(1), 230-239. [doi: 10.4319/lo.2007.52.1.0230]
    Charette, M. A., Gonneea, M. E., Morris, P. J., Statham, P., Fones, G., Planquette, H., Salter, I., and Garabato, A. N. 2007. Radium isotopes as tracers of iron sources fueling a southern ocean phytoplankton bloom. Deep-Sea Research II, 54(18-20), 1989-1998. [doi: 10.1016/j.dsr2.2007.06.003]
    Chen, C. T. A., Wang, S. L., Wang, B. J., and Pai, S. C. 2001. Nutrient budgets for the South China Sea basin. Marine Chemistry, 75(4), 281-300. [doi: 10.1016/S0304-4203(01)00041-X]
    Cochran, J. K. 1992. The oceanic chemistry of uranium and thorium series nuclides. Uranium-series Disequilibrium: Applications to Earth, Marine and Environmental Science, 334-395. Oxford: Clarendon Press.
    Colbert, S. L., and Hammond, D. E. 2007. Temporal and spatial variability of radium in the coastal ocean and its impact on computation of nearshore cross-shelf mixing rates. Continental Shelf Research, 27(10-11), 1477-1500. [ doi: 10.1016/j.csr.2007.01.003]
    Dimova, N., Dulaiova, H., Kim, G., and Burnett, W. C. 2007. Uncertainties in the preparation of 224Ra Mn fiber standards. Marine Chemistry, 109(3-4), 220-225. [doi: 10.1016/j.marchem.2007.06.016]
    Elsinger, R. J., and Moore, W. S. 1983. 224Ra, 228Ra and 226Ra in Winyah Bay and Delaware Bay. Earth and Planetary Science Letter, 64(3), 430-436. [doi: 10.1016/0012-821X(83)90103-6]
    Elsinger, R. J., and Moore, W. S. 1984. 226Ra and 228Ra in the mixing zones of the Pee Dee River-Winyah Bay, Yangtze River and Delaware Bay estuaries. Estuarine, Coastal and Shelf Science, 18(6), 601-613. [doi: 10.1016/0272-7714(84)90033-7]
    Gonneea, M. E., Morris, P. J., Dulaiova, H., and Charette, M. A. 2008. New perspectives on radium behavior within a subterranean estuary. Marine Chemistry, 109(3-4), 250-267. [doi:10.1016/j. marchem.2007.12.002]
    Hancock, G. J., and Martin, P. 1991. Determination of Ra in environmental samples by alpha-particle spectrometry. Applied Radiation and Isotopes, 42, 63-69. [doi: 10.1016/0883-2889(91)90125-K]
    Huang, Y. P., Xie, Y. Z., Chen, M., Chen, F. Z., and Qiu, Y. S. 1996. Distribution feature of 228Ra in surface seawater of the Nansha Sea area. Isotope Marine Chemistry of Nansha Islands Waters, 70-78. Beijing: China Ocean Press. (in Chinese)
    Huang, Y. P., Jiang, D. S., Xu, M. Q., Chen, M., and Qiu, Y. S. 1997. A study on horizontal eddy diffusion in the surface water of the northeastern South China Sea based on 228Ra tracer. Tropic Oceanology, 16(2), 67-74. (in Chinese)
    Huh, C. A., and Ku, T. L. 1997. A 2-D section of 228Ra and 226Ra in the Northeast Pacific. Oceanologica Acta, 21(4), 533-542. [doi: 10.1016/S0399-1784(98)80036-4]
    Hussain, N., Church, T. M., and Kim, G. 1999. Use of 222Rn and 226Ra to trace groundwater discharge into the Chesapeake Bay. Marine Chemistry, 65(1-2), 127-134. [ doi: 10.1016/S0304-4203(99)00015-8]
    Kasemsupaya, V., Tsubota, H., and Nozaki, Y. 1993. 228Ra and its implications in the Seto InIand Sea. Estuarine, Coastal and Shelf Science, 36(1), 31-45. [ doi: 10.1006/ecss.1993.1003]
    Kaufman, A., Trier, R. M., Broecker, W. S., and Feely, H. W. 1973. Distribution of 228Ra in the world ocean. Journal of Geophysical Research, 78(36), 8827-8848. [doi: 10.1029/JC078i036p08827]
    Key, R. M., Sarmiento, J. L., Stallard, R. F., and Moore, W. S. 1985. Distribution and flux of 226Ra and 228Ra in the Amazon River Estuary. Journal of Geophysical Research, 90(C10), 6995-7004. [doi: 10.1029/JC090iC04p06995]
    Kim, G., Ryu, J. W., Yang, H. S., and Yun, S. T. 2005. Submarine groundwater discharge (SGD) into the Yellow Sea revealed by 228Ra and 226Ra isotopes: Implications for global silicate fluxes. Earth and Planetary Science Letters, 237(1-2), 156-166. [doi: 10.1016/j.epsl.2005.06.011]
    Knauss, K. G., Ku, T. L., and Moore, W. S. 1978. Radium and thorium isotopes in the surface water of the East Pacific and coastal Southern California. Earth and Planetary Science Letters, 39(2), 235-249. [doi: 10.1016/0012-821X(78)90199-1]
    Krest, J. M., Moore, W. S., and Gardner, L. R. 1999. 226Ra and 228Ra in the mixing zones of the Mississippi and Atchafalaya rivers: Indicators of groundwater input. Marine Chemistry, 64(3), 129-152. [doi:10.1016/ S0304-4203(98)00070-X]
    Lee, J. S., Kim, K. H., and Moon, D. S. 2005. Radium isotopes in the Ulsan Bay. Journal of Environmental Radioactivity, 82(2), 129-141. [ doi: 10.1016/j.jenvrad.2004.11.005]
    Mao, L. M., Zhang, Y. L., and Bi, H. 2006. Modern pollen deposits in coastal mangrove swamps from northern Hainan Island, China. Journal of Coastal Research, 22(6), 1423-1436. [doi:10.2112/05- 0516.1]
    Men, W., Wei, H., and Liu, G. S. 2006. 226Ra and 228Ra in the seawater of the western Yellow Sea. Journal of Ocean University of China, 5(3), 228-234.
    Moore, W. S., Feely, H. W., and Li, Y. H. 1980. Radium isotopes in sub-Arctic waters. Earth and Planetary Science Letter, 49(2), 329-340. [ doi: 10.1016/0012-821X(80)90076-X]
    Moore, W. S. 1997. High fluxes of radium and barium from the mouth of the Ganges-Brahmaputra River during low river discharge suggest a large groundwater source. Earth and Planetary Science Letter, 150(1-2), 141-150. [ doi: 10.1016/S0012-821X(97)00083-6]
    Moore, W. S. 1999. The subterranean estuary: a reaction zone of ground water and sea water. Marine Chemistry, 65(1-2), 111-125. [ doi: 10.1016/S0304-4203(99)00014-6]
    Moore, W. S. 2000. Determining coastal mixing rates using radium isotopes. Continental Shelf Research, 20(15), 1993-2007. [ doi: 10.1016/S0278-4343(00)00054-6]
    Nakada, S., Yasumoto, J., Taniguchi, M., and Ishitobi, T. 2011. Submarine groundwater discharge and seawater circulation in a subterranean estuary beneath a tidal flat. Hydrological Processes, published online at http://onlinelibrary.wiley.com/doi/10.1002/hyp.8016/abstract on March 24, 2011. [doi:10. 1002/hyp.8016]
    Okubo, A. 1971. Oceanic diffusion diagrams. Deep-Sea Research and Oceanographic Abstracts, 18(8), 789-802. [ doi: 10.1016/0011-7471(71)90046-5]
    Peterson, R. N., Burnett, W. C., Taniguchi, M., Chen, J. Y., Santos, I. R., and Ishitobi, T. 2008. Radon and radium isotope assessment of submarine groundwater discharge in the Yellow River Delta, China. Journal of Geophysical Research, 113(C9), C09021. [doi: 10.1029/2008JC004776]
    Rengarajan, R., Sarin, M. M., Somayajulu, B. L. K., and Suhasini, R. 2002. Mixing in the surface waters of the western Bay of Bengal using 228Ra and 226Ra. Journal of Marine Research, 60(2), 255-279.
    Schmidt, S., and Reyss, J. L. 1996. Radium as an internal tracer of Mediterranean outflow water. Journal of Geophysical Research, 101(C2), 3589-3596. [doi: 10.1029/95JC03308]
    Somayajulu, B. L. K., Sarin, M. M., and Ramesh, R. 1996. Denitrification in the eastern Arabian Sea: Evaluation of the role of continental margins using Ra isotopes. Deep-Sea Research II, 43(1), 111-117. [doi: 10.1016/0967-0645(95)00079-8]
    Swarzenski, P. W. 2007. U/Th series radionuclides as coastal groundwater tracers. Chemical Reviews, 38(21), 663-674. [doi: 10.1002/chin.200721270]
    van Beek, P., Bourquin, M., Reyss, J. L., Souhaut, M., Charette, M. A., and Jeandel, C. 2008. Radium isotopes to investigate the water mass pathways on the Kerguelen Plateau (Southern Ocean). Deep-Sea Research II, 55(5-7), 622-637. [doi: 10.1016/j.dsr2.2007.12.025]
    van der Loeff, M. M. R., Key, R. M., Scholten, J., Bauch, D., and Michel, A. 1995. 228Ra as a tracer for shelf water in the Arctic Ocean. Deep-Sea Research II, 42 (6), 1533-1553. [doi:10.1016/0967-0645(95) 00053-4]
    Wang, B. C., Chen, S. L., Gong, W. P., Ling, W. Q., and Xu, Y. 2006. Development and Evolution of Estuarine coast in Hainan Island. Beijing: China Ocean Press. (in Chinese)
    Wang, Y. 2002. Features of Hainan Island coastal environment. Marine Geology Letters, 18(3), 1-9. (in Chinese)
    Xie, Y. Z., Huang, Y. P., Shi, W. Y., Fu, Z. L., Qiu, Y. S., Xiao, Y., Chen, M., and Chen, F. Z. 1995. 228Ra in the NE South China Sea. Proceedings of Symposium of Marine Sciences in Taiwan Strait and Its Adjacent Waters, 232-239. Beijing: China Ocean Press. (in Chinese)
    Yamada, M., and Nozaki, Y. 1986. Radium isotopes in coastal and open ocean surface waters of the western North Pacific. Marine Chemistry, 19(4), 379-389. [ doi: 10.1016/0304-4203(86)90057-5]
    Yang, H. S., Hwang, D. W., and Kim, G. 2002. Factors controlling excess radium in the Nakdong River Estuary, Korea: Submarine groundwater discharge versus desorption from riverine particles. Marine Chemistry, 78(1), 1-8. [ doi: 10.1016/S0304-4203(02)00004-X]
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (2644) PDF downloads(3396) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return