Volume 6 Issue 3
Jul.  2013
Turn off MathJax
Article Contents
Article Navigation >  Water Science and Engineering  > 2013  >  6(3): 262-271
Yang XIAO, Xiao-lian ZHU, Hao-ke CHENG, Kai-jie LI, Qi LU, Dong-fang LIANG. 2013: Characteristics of phosphorus adsorption by sediment mineral matrices with different particle sizes. Water Science and Engineering, 6(3): 262-271. doi: 10.3882/j.issn.1674-2370.2013.03.003
Citation: Yang XIAO, Xiao-lian ZHU, Hao-ke CHENG, Kai-jie LI, Qi LU, Dong-fang LIANG. 2013: Characteristics of phosphorus adsorption by sediment mineral matrices with different particle sizes. Water Science and Engineering, 6(3): 262-271. doi: 10.3882/j.issn.1674-2370.2013.03.003
shu

Characteristics of phosphorus adsorption by sediment mineral matrices with different particle sizes

doi: 10.3882/j.issn.1674-2370.2013.03.003
  • 1.

    State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Hohai University, Nanjing 210098, P. R. China

  • 2.

    College of Water Conservancy and Hydropower Engineering, Hohai University, Nanjing 210098, P. R. China

  • 3.

    National Engineering Research Center of Water Resources Efficient Utilization and Engineering Safety, Hohai University, Nanjing 210098, P. R. China

  • 4.

    Department of Engineering Mechanics, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

  • 5.

    MOE Key Laboratory of Hydrodynamics, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Funds:  This work was supported by the National Natural Science Foundation of China (Grants No. 51179055, 51239003, and 51125034), and the Special Fund of State Key Laboratory of China (Grant No. 2010585512).
More Information
  • Corresponding author: Kai-jie LI
  • Received Date: 2013-04-24
  • Rev Recd Date: 2013-06-04
    Abstract
  • The particle size of sediment is one of the main factors that influence the phosphorus physical adsorption on sediment. In order to eliminate the effect of other components of sediment on the phosphorus physical adsorption, the sediment mineral matrices were obtained by removing inorganic matter, metal oxides, and organic matter from natural sediments, which were collected from the Nantong reach of the Yangtze River. The results show that an exponential relationship exists between the median particle size (D50) and specific surface area (Sg) of the sediment mineral matrices, and the fine sediment mineral matrix sample has a larger specific surface area and pore volume than the coarse sediment particles. The kinetic equations were used to describe the phosphorus adsorption process of the sediment mineral matrices, including the Elovich equation, quasi-first-order adsorption kinetic equation, and quasi-second-order adsorption kinetic equation. The results show that the quasi-second-order adsorption kinetic equation has the best fitting effect. Using the mass conservation and Langmuir adsorption kinetic equations, a formula was deduced to calculate the equilibrium adsorption capacity of the sediment mineral matrices. The results of this study show that the phosphorus adsorption capacity decreases with the increase of D50, indicating that the specific surface area and pore volume are the main factors in determining the phosphorus adsorption capacity of the sediment mineral matrices. This study will help understand the important role of sediment in the transformation of phosphorus in aquatic environments.

     

    • FullText(HTML)
  • loading
    • References(17)
  • Chien, S. H., and Clayton, W. R. 1980. Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Science Society of America Journal, 44(2), 265-268. [doi:10.2136/sssaj1980. 03615995004400020013x]
    Evans, D. J., Johnes, P. J., and Lawrence, D. S. 2004. Physico-chemical controls on phosphorus cycling in two lowland streams. Part 2: The sediment phase. Science of the Total Environment, 329(1-3), 165-182. [doi: 10.1016/j.scitotenv.2004.02.023]
    Fang, H. W., Chen, M. H., and Chen, Z. H. 2008. Surface pore tension and adsorption characteristics of polluted sediment. Science in China Series G: Physics, Mechanics and Astronomy, 51(8), 1022-1028. [doi: 10.1007/s11433-008-0104-8]
    House, W. A., Denison, F. H., Smith, J. T., and Armitage, P. D. 1995. An investigation of the effects of water velocity on inorganic phosphorus influx to a sediment. Environmental Pollution, 89(3), 263-271. [doi: 10.1016/0269-7491(94)00071-K]
    Huang, S. L. 2003. Investigation of cadmium desorption from different-sized sediments. Journal of Environmental Engineering, 129(3), 241-247. [doi: 10.1061/(ASCE)0733-9372(2003)129:3(241)]
    Jenne, E. A. 1968. Controls on Mn, Fe, Co, Ni, Cu, and Zn concentrations in soils and water: The significant role of hydrous Mn and Fe oxides. Advance in Chemistry, 73, 337-387. [doi:10.1021/ ba-1968-0073.ch021]
    Jin, X. C., Wang, S. R., Pang, Y., Zhao, H. C., and Zhou, X. N. 2005. The adsorption of phosphate on different trophic lake sediments. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 254(1-3), 241-248. [doi: 10.1016/j.colsurfa.2004.11.016]
    Koeppenkastrop, D., and De Carlo, E. H. 1992. Sorption of rare-earth elements from seawater onto synthetic mineral particles: An experimental approach. Chemical Geology, 95(3-4), 251-263. [doi:10.1016/ 0009-2541(92)90015-W]
    Murphy, J., and Riley, J. P. 1962. A modified single solution method for the determination of phosphate in natural waters. Analytica Chimica Acta, 27, 31-36. [doi: 10.1016/S0003-2670(00)88444-5]
    Sánchez-Martín, M. J., Dorado, M. C., Del Hoyo, C., and Rodríguez-Cruz, M. S. 2008. Influence of clay mineral structure and surfactant nature on the adsorption capacity of surfactants by clays. Journal of Hazardous Materials, 150(1), 115-123. [doi: 10.1016/j.jhazmat.2007.04.093]
    Schroth, B. K., and Sposito, G. 1998. Effect of landfill leachate organic acids on trace metal adsorption by kaolinite. Environmental Science and Technology, 32(10), 1404-1408. [doi: 10.1021/es970587q]
    Tang, H. X., Xue, H. B., Lin, G. Z., Gao, L., Tian, B. Z., Lei, P. J., Dong, X. R., and Cao, F. C. 1981. Adsorption characteristics of cadmium pollutants on the chinese clay minerals. Acta Scientiae Circumstantiae, 1(2), 140-155. (in Chinese)
    Wang, S. R., Jin, X. C., Zhao, H., Zhou, X. C., and Wu, F. C. 2007. Effect of organic matter on the sorption of dissolved organic and inorganic phosphorus in lake sediments. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 297(1-3), 154-162. [doi: 10.1016/j.colsurfa.2006.10.040]
    Wang, X. Y., Zhang, L. P., Zhang, H. S., Wu, X. Y., and Mei, D. L. 2012. Phosphorus adsorption characteristics at the sediment-water interface and relationship with sediment properties in FUSHI reservoir, China. Environmental Earth Sciences, 67(1), 15-22. [doi: 10.1007/s12665-011-1476-z]
    Wang, Y., Shen, Z., Niu, J., and Liu, R. 2009. Adsorption of phosphorus on sediments from the Three-Gorges Reservoir (China) and the relation with sediment compositions. Journal of Hazardous Materials, 162(1), 92-98. [doi: 10.1016/j.jhazmat.2008.05.013]
    Withers, P. J. A., and Jarvie, H. P. 2008. Delivery and cycling of phosphorus in rivers: A review. Science of the Total Environment, 400(1-3), 379-395. [doi: 10.1016/j.scitotenv.2008.08.002]
    Zhang, J., Huang, W. W., Liu, M. G., and Zhou, Q. 1990. Drainage basin weathering and major element transport of two large Chinese rivers (Huanghe and Changjiang). Journal of Geophysical Research: Oceans, 95(C8), 13277-13288. [doi: 10.1029/JC095iC08p13277]
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (2839) PDF downloads(3338) Cited by()
    Proportional views
    Related

    Copyright © 2009 Editorial office of Water Science and Engineering 苏ICP备12023610号-1

    Supported by: Beijing Renhe Information Technology Co. Ltd   support: info@rhhz.net

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return