Volume 19 Issue 2
May  2026
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Rajaa Zahnoune, Otmane Boudouch, Radouane El Amri, Abdelfattah El Mahbouby, Maryeme Hamdouch, Reda Elkacmi. 2026: Synergistic electrocoagulation in a self-induced airlift reactor: A leap towards energy-efficient and sustainable tannery wastewater remediation. Water Science and Engineering, 19(2): 198-210. doi: 10.1016/j.wse.2026.02.002
Citation: Rajaa Zahnoune, Otmane Boudouch, Radouane El Amri, Abdelfattah El Mahbouby, Maryeme Hamdouch, Reda Elkacmi. 2026: Synergistic electrocoagulation in a self-induced airlift reactor: A leap towards energy-efficient and sustainable tannery wastewater remediation. Water Science and Engineering, 19(2): 198-210. doi: 10.1016/j.wse.2026.02.002

Synergistic electrocoagulation in a self-induced airlift reactor: A leap towards energy-efficient and sustainable tannery wastewater remediation

doi: 10.1016/j.wse.2026.02.002
  • Received Date: 2025-07-30
  • Accepted Date: 2026-01-11
  • Available Online: 2026-05-30
  • Tannery wastewater is a challenging effluent due to its high concentrations of chromium, total sulfides, and recalcitrant organic compounds. This study presented a novel electrocoagulation (EC) process using a self-induced external-loop airlift reactor (ELAR), which operated without mechanical mixing and relied on hydrogen and oxygen microbubbles for internal circulation. Under optimal conditions (pH of 6, a current density of 50 mA/cm2, an electrolysis time of 20 min), the ELAR achieved high pollutant removal efficiencies (88% chemical oxygen demand (COD) removal and 92% Cr removal) with lower energy consumption (10.8 kW·h/m3) and reduced operational costs (1.83 USD per cubic meter) compared to a stirred tank reactor. Artificial neural network (ANN) modeling enabled data-driven optimization, further improving COD removal to 94% with reducing energy input. Kinetic and isotherm analyses confirmed chemisorption as the dominant mechanism. Life cycle assessment (LCA) and solar integration scenarios highlighted the environmental benefits of the ELAR system. Sludge characterization indicated potential for reuse as construction materials. This study uniquely introduced an ELAR system that operates without mechanical agitation, combined with ANN modeling and LCA, representing the first integrated approach for optimizing and assessing EC performance in tannery wastewater treatment. These findings demonstrate that the ELAR system offers a cost-effective and sustainable solution for industrial wastewater remediation.

     

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  • [1]
    Al-Qodah, Z., Al-Shannag, M., Al-Degs, Y., Al-Rimawi, F., Al-Qudah, N., 2025a. Performance of continuous electrocoagulation processes (CEPs) as an efficient approach for the treatment of industrial organic pollutants: A comprehensive review. Water 17(15), 2351. https://doi.org/10.3390/w17152351.
    [2]
    Al-Qodah, Z., Al-Shannag, M., Al-Degs, Y., Al-Qudah, N., 2025b. Continuous electrocoagulation processes for industrial inorganic pollutants removal: A critical review of performance and applications. Water 17(17), 2639. https://doi.org/10.3390/w17172639.
    [3]
    American Public Health Association (APHA), 2017. Standard Methods for the Examination of Water and Wastewater, 23rd Edition. APHA, Washington, DC. https://doi.org/10.2105/SMWW.2882.001.
    [4]
    Apaydin, O., Kurt, U., Gonullu, M.T., 2009. An investigation on the treatment of tannery wastewater by electrocoagulation. Global NEST Journal 11(4), 546-555. https://doi.org/10.30955/gnj.000547.
    [5]
    Asaithambi, P., Yesuf, M.B., Govindarajan, R., Selvakumar, P., Niju, S., Pandiyarajan, T., Alemayehu, E., 2023. Industrial wastewater treatment using batch recirculation electrocoagulation (BRE) process: Studies on operating parameters. Sustainable Chemistry and Environment 2, 100014. https://doi.org/10.1016/j.scmr.2023.100014.
    [6]
    Bingol, Z., Irdemez, S., Yildiz, Y., Demircioglu, N., 2023. Organic and inorganic matter removal from tannery wastewater using the electrocoagulation process. International Journal of Environmental Science and Technology 20, 2171-2180. https://doi.org/10.1007/s13762-022-04144-5.
    [7]
    Chang, Z., Long, G., Zhou, J.L., Ma, C., 2020. Valorization of sewage sludge in the fabrication of construction and building materials: A review. Resources, Conservation and Recycling 154, 104606. https://doi.org/10.1016/j.resconrec.2019.104606.
    [8]
    Choudhary, V., Goyal, H., Varma, A.K., Shankar, R., Chakma, S., Malviya, P., Thakur, L.S., 2024. Life cycle assessment (LCA) of the lead, chromium, and cadmium removal from water through electrocoagulation. Materials Today: Proceedings 111, 8-14. https://doi.org/10.1016/j.matpr.2023.08.297.
    [9]
    Durai, G., Rajasimman, M., 2011. Biological treatment of tannery wastewater: A review. Journal of Environmental Science and Technology 4(1), 1-17. https://doi.org/10.3923/jest.2011.1.17.
    [10]
    Elkacmi, R., Bennajah, M., 2019. Advanced oxidation technologies for the treatment and detoxification of olive mill wastewater: A general review. Journal of Water Reuse and Desalination 9(4), 463-505. https://doi.org/10.2166/wrd.2019.033.
    [11]
    Elkacmi, R., Boudouch, O., Hasib, A., Bouzaid, M., Bennajah, M., 2020. Photovoltaic electrocoagulation treatment of olive mill wastewater using an external-loop airlift reactor. Sustainable Chemistry and Pharmacy 17, 100274. https://doi.org/10.1016/j.scp.2020.100274.
    [12]
    Environmental Protection Agency (EPA), 1992. Method 7196A: Chromium, hexavalent (colorimetric). In: Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), 3rd Edition, Update III. EPA Publication No. SW-846. EPA, Washington DC.
    [13]
    Gokkus, O., Brillas, E., Sires, I., 2024. Sequential use of a continuous-flow electrocoagulation reactor and a (photo)electro-Fenton recirculation system for the treatment of Acid Brown 14 diazo dye. Science of The Total Environment 912, 169143. https://doi.org/10.1016/j.scitotenv.2023.169143.
    [14]
    Goyal, H., Mondal, P., 2022. Life cycle assessment (LCA) of arsenic and fluoride removal from groundwater through adsorption and electrocoagulation: A comparative study. Chemosphere 304, 135243. https://doi.org/10.1016/j.chemosphere.2022.135243.
    [15]
    International Organization for Standardization (ISO), 2006a. ISO 14040:2006. Environmental Management - Life Cycle Assessment - Principles and Framework. ISO, Geneva. https://doi.org/10.3403/01139131.
    [16]
    International Organization for Standardization (ISO), 2006b. ISO 14044:2006. Environmental Management - Life Cycle Assessment - Requirements and Guidelines. ISO, Geneva. https://doi.org/10.3403/30290345.
    [17]
    Juel, M.A.I., Mizan, A., Ahmed, T., 2017. Sustainable use of tannery sludge in brick manufacturing in Bangladesh. Waste Management 60, 259-269. https://doi.org/10.1016/j.wasman.2016.12.041.
    [18]
    Kobya, M., Gengec, E., Demirbas, E., 2015. Operating parameters and cost assessments of a real dyehouse wastewater effluent treated by a continuous electrocoagulation process. Chemical Engineering and Processing: Process Intensification 91, 87-100. https://doi.org/10.1016/j.cep.2015.03.012.
    [19]
    Lofrano, G., Meric, S., Zengin, G.E., Orhon, D., 2013. Chemical and biological treatment technologies for leather tannery chemicals and wastewaters: A review. Science of The Total Environment 461-462, 265-281. https://doi.org/10.1016/j.scitotenv.2013.05.004.
    [20]
    Mollah, M.Y.A., Schennach, R., Parga, J.R., Cocke, D.L., 2004. Electrocoagulation (EC): Science and applications. Journal of Hazardous Materials 84(1), 29-41. https://doi.org/10.1016/S0304-3894(01)00276-5.
    [21]
    Nath, S., 2024. Electrochemical wastewater treatment technologies through life cycle assessment: A review. ChemBioEng Reviews 11(4), e202400016. https://doi.org/10.1002/cben.202400016.
    [22]
    Nidheesh, P.V., Gokkus, O., 2023. Aerated iron electrocoagulation process as an emerging treatment method for natural water and wastewater. Separation Science and Technology 58(11), 2041-2063. https://doi.org/10.1080/01496395.2023.2227913.
    [23]
    Patel, P., Gupta, S., Mondal, P., 2023. Life cycle assessment (LCA) of greywater treatment using ZnCl2 impregnated activated carbon and electrocoagulation processes: A comparative study. Industrial & Engineering Chemistry Research 62(7), 3259-3270. https://doi.org/10.1021/acs.iecr.2c03353.
    [24]
    Rajaniemi, K., Tuomikoski, S., Lassi, U., 2021. Electrocoagulation sludge valorization-A review. Resources 10(12), 127. https://doi.org/10.3390/resources10120127.
    [25]
    Sivaram, N.M., Barik, D., 2019. Chapter 5 - Toxic waste from leather industries. In: Barik, D. (Ed.), Energy from Toxic Organic Waste for Heat and Power Generation. Woodhead Publishing, Duxford, pp. 55-67. https://doi.org/10.1016/B978-0-08-102528-4.00005-5.
    [26]
    Valdiviezo-Gonzales, L., Mancco, F.A., Cartolin, A.P., Molina, J.M., Torres, R.J.C., Quispe, P.R., 2023. Kinetic study of electrocoagulation of tannery wastewater. Chemical Engineering Transactions 98, 69-74. https://doi.org/10.3303/CET2398012.
    [27]
    Villalobos-Lara, A.D., Perez, T., Uribe, A.R., Alfaro-Ayala, J.A., Ramirez-Minguela, J.J., 2021. Electrocoagulation treatment of industrial tannery wastewater employing a modified rotating cylinder electrode reactor. Journal of Environmental Chemical Engineering 9(4), 105283. https://doi.org/10.1016/j.jece.2021.105283.
    [28]
    Zahnoune, R., Boudouch, O., Elamri, R., El-ghozlani, M., Kamil, N., Elkacmi, R., 2025. Optimized electrocoagulation and kinetic study for continuous treatment of fresh landfill leachate in an external-loop airlift reactor. Chemical Engineering Science 317, 122115. https://doi.org/10.1016/j.ces.2025.122115.
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