Volume 7 Issue 4
Oct.  2014
Turn off MathJax
Article Contents
Wen-sheng XU, Li CHEN, Xiao-xia TONG, Xiao-ping CHEN, Ping-cang ZHANG. 2014: Experimental study on desorption of soluble matter as influenced by cations in static water. Water Science and Engineering, 7(4): 384-394. doi: 10.3882/j.issn.1674-2370.2014.04.004
Citation: Wen-sheng XU, Li CHEN, Xiao-xia TONG, Xiao-ping CHEN, Ping-cang ZHANG. 2014: Experimental study on desorption of soluble matter as influenced by cations in static water. Water Science and Engineering, 7(4): 384-394. doi: 10.3882/j.issn.1674-2370.2014.04.004

Experimental study on desorption of soluble matter as influenced by cations in static water

doi: 10.3882/j.issn.1674-2370.2014.04.004
Funds:  This work was supported by the National Natural Science Foundation of China (Grant No. 51209014) and the Fundamental Research Funds for the Changjiang River Scientific Research Institute (Grant No. CKSF2013012/TB).
More Information
  • Corresponding author: Wen-sheng XU
  • Received Date: 2013-09-16
  • Rev Recd Date: 2014-09-01
  • With variation of drainage basin environments, desorption of soluble matter has become one of the significant erosion processes in rivers. It has a considerable impact on flow and sediment transport, as well as processes of river bed deformation and landform evolution throughout a watershed. In this study, considering influences on sediment movement, especially on cohesive sediment transport, Ca2+ and H+ were chosen as characteristic ions of soluble matter, and the total desorption quantity of Ca2+ and pH value when the desorption equilibrium is reached were employed as two indexes representing the desorption of soluble matter. By means of an indoor experiment, desorption of soluble matter as influenced by cations in static water was investigated. The results show that the total desorption quantity of soluble matter increases with the initial cation concentration until a maximum desorption quantity value is obtained and maintained. The total desorption quantity of soluble matter depends on properties of the specific cations in static water, and the stronger the affinity is between the cation and sediment surface, the higher the total desorption quantity will be. Finally, a strong approximate linear relationship between desorption quantities for different kinds of soluble matters was obtained, which means that variation of pH values can accurately reflect the desorption results of soluble matter.
     
     

     

  • loading
  • Arias, M., Pérez-Novo, C., Osorio, F., López, E., and Soto, B. 2005. Adsorption and desorption of copper and zinc in the surface layer of acid soils. Journal of Colloid and Interface Science, 288(1), 21-29. [doi: 10.1016/j.jcis.2005.02.053]
    Chen, J. S., Wang, F. Y., Meybeck, M., He, D. W., Xia, X. H., and Zhang, L. T. 2005. Spatial and temporal analysis of water chemistry records (1958-2000) in the Huanghe (Yellow River) basin. Global Biogeochemical Cycles,19(3), 1-24 (GB3016). [doi: 10.1029/2004GB002325]
    Chen, J. S. 2006. Principle of Water Quality in Rivers and Water Quality of Rivers in China. Beijing: Science Press. (in Chinese)
    Hurwitz, S., Evans, W. C., and Lowenstern, J. B. 2010. River solute fluxes reflecting active hydrothermal chemical weathering of the Yellowstone Plateau Volcanic Field, USA. Chemical Geology, 276(3-4), 331-343. [doi: 10.1016/j.chemgeo.2010.07.001]
    Li, S. Y., Lu, X. X., He, M., Zhou, Y., Bei, R. T., Li, L., and Ziegler, A. D. 2011. Major element chemistry in the upper Yangtze River: A case study of the LongchuanjiangRiver. Geomorphology, 129(1-2), 29-42. [doi: 10.1016/j.geomorph.2011.01.010]
    Li, X. Y. 2001. Soil Chemistry. Beijing: Higher Education Press. (in Chinese)
    Meybeck, M., and Helmer, R. 1989. The quality of rivers: From pristine stage to global pollution. Palaeogeography, Palaeoclimatology, Palaeoecology, 75(4), 283-309. [doi:10.1016/0031-0182 (89)90191-0]
    Reczynski, W., Jakubowska, M., Golas, J., Parker, A., and Kubica, B. 2010. Chemistry of sediments from the Dobczyce Reservoir, Poland, and the environmental implications. International Journal of Sediment Research, 25(1), 28-38. [doi: 10.1016/S1001-6279(10)60025-X]
    Semenov, M. Y., and Zimnik, E. A. 2010. Use of chemical composition of surface waters in estimating contributions from dissolved matter sources. Geography and Natural Resources, 31(2), 170-176. [doi: 10.1016/j.gnr.2010.06.013]
    Shaw, D. J. 1992. Introduction to Colloid and Surface Chemistry. 4th ed.New York: Elsevier Scientific Publishing Company.
    Singh, D., McLaren, R. G., and Cameron, K. C. 2006. Zinc sorption-desorption by soils: Effect of concentration and length of contact period. Geoderma, 137(1-2), 117-125. [doi:10.1016/j.geoderma. 2006.08.002]
    Soumya, B. S., Sekhar, M., Riotte, J., Audry, S., Lagane, C., and Braun, J. J. 2011. Inverse models to analyze the spatiotemporal variations of chemical weathering fluxes in a granito-gneissic watershed: Mule Hole, South India. Geoderma, 165(1), 12-24. [doi: 10.1016/j.geoderma.2011.06.015]
    Tran, Y. T., Barry, D. A. and Bajracharya, K. 2002. Cadmium desorption in sand. Environment International, 28(6), 493-502. [doi: 10.1016/S0160-4120(02)00077-6]
    Viers, J., Dupré, B., and Gaillardet, J. 2009. Chemical composition of suspended sediments in World Rivers: New insights from a new database. Science of the Total Environment, 407(2), 853-868. [doi: 10.1016/j.scitotenv.2008.09.053]
    Wang, J. S., Chen, L., Fan, B. L., and Chai, X. L. 2009a. Relationship between ion transport and sediment discharge in river. Advances in Water Science, 20(5), 658-662. (in Chinese)
    Wang, R. M., You, C. F., Chu, H. Y., and Hung, J. J. 2009b. Seasonal variability of dissolved major and trace elements in the Gaoping (Kaoping) River Estuary, Southwestern Taiwan. Journal of Marine Systems, 76(4), 444-456. [doi: 10.1016/j.jmarsys.2007.11.012]
    Wei, F. S. 1997. Monitoring and Analysis Method Guide for Water and Wastewater. Beijing: China Environmental Science Press. (in Chinese)
    Xu, W. S., Chen, L., Liu, J., and Jiang, L. 2010. Analysis on models for predicting the desorption quantity of soluble matters in rivers. Journal of SichuanUniversity (Engineering Science Edition), 42(4), 42-47.  (in Chinese)
    Xu, W. S., Chen, L., Zhao, D. Z., and Liu, X. T. 2009. Experimental study of the effects of Na+ on the desorption of soluble chemicals in rivers. Advances in Water Science, 20(4), 537-543. (in Chinese)
    Yang, S. Y., Liu, S. G., and Li, C. X. 2000. Chemical fluxes of asian rivers into the ocean and their controlling factors. Marine Science Bulletin, 19(4), 22-28. (in Chinese)
    Zhou, J., Liu, G. H., Pan, M. Q., Zhai, B., and He, J. L. 1999. Study on vegetation and its succession on Luojia Hill, Wuhan, Wuhan I: Status quo of vegetation.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (1963) PDF downloads(1745) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return