2024 Vol. 17, No. 1

Water Resources
Abstract:

Coastal management in China is confronted with an urgent choice between natural restoration and maintenance of existing seawalls and reclaimed land for economic development. A key criterion for making this decision is the resilience to coastal flooding, which depends on the ability to predict tidal level. Tidal duration asymmetry (TDA) is a key parameter in determination of the arrival and duration of flood tides. This study selected the western inner shelf of the Yellow Sea (WYS) as the study area and investigated the responses of TDA to different shoreline configurations and relative sea level rise. The responses of TDA to shoreline reconstruction yielded spatial variability locally and remotely. In the nearshore area, the responses of TDA to the complex ocean environment mainly originated from the combined functions of reflection, bottom friction, and advection, which controlled the energy transfer from M2 or S2 constituents to their overtides or compound tides. The sensitivity of TDA to coastline typologies was not limited to coastal waters but could stretch over the entire inner shelf. The vulnerability of tidal responses was due to the displacement of the M2 amphidrome of the Kelvin wave on the WYS, which in turn changed tidal energy fluxes over the regime. The relative sea level rise could intensify the feedback of TDA to seawalls and land reclamation.

Abstract:

Copula functions have been widely used in stochastic simulation and prediction of streamflow. However, existing models are usually limited to single two-dimensional or three-dimensional copulas with the same bivariate block for all months. To address this limitation, this study developed a mixed D-vine copula-based conditional quantile model that can capture temporal correlations. This model can generate streamflow by selecting different historical streamflow variables as the conditions for different months and by exploiting the conditional quantile functions of streamflows in different months with mixed D-vine copulas. The up-to-down sequential method, which couples the maximum weight approach with the Akaike information criteria and the maximum likelihood approach, was used to determine the structures of multivariate D-vine copulas. The developed model was used in a case study to synthesize the monthly streamflow at the Tangnaihai hydrological station, the inflow control station of the Longyangxia Reservoir in the Yellow River Basin. The results showed that the developed model outperformed the commonly used bivariate copula model in terms of the performance in simulating the seasonality and interannual variability of streamflow. This model provides useful information for water-related natural hazard risk assessment and integrated water resources management and utilization.

Aquatic Environment
Abstract:

Increasing bacteria levels in the Lower Neches River caused by Hurricane Harvey has been of a serious concern. This study is to analyze the historical water sampling measurements and real-time water quality data collected with wireless sensors to monitor and evaluate water quality under different hydrological and hydraulic conditions. The statistical and Pearson correlation analysis on historical water samples determines that alkalinity, chloride, hardness, conductivity, and pH are highly correlated, and they decrease with increasing flow rate due to dilution. The flow rate has positive correlations with Escherichia coli, total suspended solids, and turbidity, which demonstrates that runoff is one of the causes of the elevated bacteria and sediment loadings in the river. The correlation between E. coli and turbidity indicates that turbidity greater than 45 nephelometric turbidity units in the Neches River can serve as a proxy for E. coli to indicate the bacterial outbreak. A series of statistical tools and an innovative two-layer data smoothing filter are developed to detect outliers, fill missing values, and filter spikes of the sensor measurements. The correlation analysis on the sensor data illustrates that the elevated sediment/bacteria/algae in the river is either caused by the first flush rain and heavy rain events in December to March or practices of land use and land cover. Therefore, utilizing sensor measurements along with rainfall and discharge data is recommended to monitor and evaluate water quality, then in turn to provide early alerts on water resources management decisions.

Abstract:

Sodium hypochlorite has significant potential as a sanitation solution in hard-to-reach areas. Few studies have investigated the optimal electrolysis parameters for its production with volumes greater than 10 L. This study evaluated sodium hypochlorite production through electrolysis in a 22-L prototype and identified the optimal operating parameters. Tests were performed using graphite electrodes with areas of 68.4 cm2 at the laboratory scale and 1 865.0 cm2 at the prototype scale. A design for experiments with different operating times, chloride concentrations, and electric current intensities was developed. The optimal operating time, sodium chloride concentration, and current intensity at the laboratory scale were 120 min, 150 g of chloride per liter, and 3 A, respectively, leading to the production of 5.02 g/L of the disinfectant with an energy efficiency of 12.21 mg of Cl2 per kilojoule. At the prototype scale, the maximum sodium hypochlorite concentration of 3.99 g of chloride per liter was achieved with an operating time of 120 min, a sodium chloride concentration of 100 g of chloride per liter, and a current intensity of 70 A, reaching an energy efficiency of 42.56 mg of Cl2 per kilojoule. In addition, this study evaluated the influences of the chloride concentration, current intensity, and operating time on the production of sodium hypochlorite at the two scales, and formulated the equations showing the trends of sodium hypochlorite production and energy efficiency in the electrochemical systems. The 22-L prototype model for production of this oxidizing substance is promising for disinfection of large volumes of water in areas that are difficult to access.

Abstract:

Pollution of rivers is mainly caused by anthropogenic activities such as discharge of effluent from industrial facilities, maintenance of sewage/effluent treatment plants, and dumping of solid waste on river banks. This study dealt with the pollution issues of the Cooum River in the well-known city of Chennai in South India. Water samples from 27 locations were collected and analyzed for 12 elements, including Ba, B, and Al, as well as heavy metals such as Pb, Cr, Mn, Fe, Co, Ni, Cu, Zn, and Cd. The samples showed levels of these elements that exceeded World Health Organization recommendations. Pearson correlation analysis revealed the inter-dependency among elements, and the contribution of each element based on factor loadings showed its percentage contribution compared to others. Water samples from six significant locations were chosen for remediation with three algae: Chlorella vulgaris, Scenedesmus dimorphus, and Phormedium sp. The uptake of pollutants led to the continuous growth of algae during the incubation period of 15 d, effectively removing heavy metals from the river water. The increasing levels of algal counts and the chlorophyll a content confirmed the algal growth during the incubation period, followed by a declining stage after the incubation period. The scanning electron microscopic images of algae before and after the remediation showed no remarkable modification of morphological patterns. This study showed that the uptake of heavy metals using algae is an effective water pollution remediation measure, making the process practicable in the field on a large scale in the near future.

Abstract:

Lignocellulose has the potential to become a bio-based adsorbent due to its biodegradability and renewability. In this study, a novel polydopamine-functionalized-lignin (lignin@PDA), prepared via self-polymerization of dopamine (PDA) on lignin, was used as a bio-based adsorbent for rapid scavenging of hexavalent chromium (Cr(VI)). The morphology, functional groups, crystalline structure, and chemical composition of lignin@PDA were characterized with a scanning electron microscope–energy dispersive spectrometer, Fourier transform infrared spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The Cr(VI) adsorption process of lignin@PDA was studied using batch experiments as a function of pH, ionic strength, adsorbent dose, and contact time at room temperature. The adsorption rate of lignin@PDA was five times greater than that of the unmodified lignin, with a maximum adsorption capacity of 102.6 mg/g in an acidic medium. The adsorption of Cr(VI) on lignin@PDA fit the pseudo-second-order equation and the Freundlich model, indicating that the adsorption process was mainly dominated by chemisorption and surface complexation. The thermodynamic parameters showed that adsorption of Cr(VI) on lignin@PDA was an endothermic and spontaneous process. The X-ray absorption fine structure results showed that sorption and reduction of Cr(VI) into Cr(III) occurred simultaneously on lignin. Moreover, PDA coating not only improved the reactivity of lignin but also promoted the complete reduction of Cr(VI) by lignin. According to these results, polydopamine-functionalized-lignin is a promising bio-based adsorbent for immobilization of Cr(VI) from wastewater.

Abstract:

Algal blooms, the spread of algae on the surface of water bodies, have adverse effects not only on aquatic ecosystems but also on human life. The adverse effects of harmful algal blooms (HABs) necessitate a convenient solution for detection and monitoring. Unmanned aerial vehicles (UAVs) have recently emerged as a tool for algal bloom detection, efficiently providing on-demand images at high spatiotemporal resolutions. This study developed an image processing method for algal bloom area estimation from the aerial images (obtained from the internet) captured using UAVs. As a remote sensing method of HAB detection, analysis, and monitoring, a combination of histogram and texture analyses was used to efficiently estimate the area of HABs. Statistical features like entropy (using the Kullback–Leibler method) were emphasized with the aid of a gray-level co-occurrence matrix. The results showed that the orthogonal images demonstrated fewer errors, and the morphological filter best detected algal blooms in real time, with a precision of 80%. This study provided efficient image processing approaches using on-board UAVs for HAB monitoring.

Water Engineering
Abstract:

A physically-based numerical three-dimensional earthen dam piping failure model is developed for homogeneous and zoned soil dams. This model is an erosion model, coupled with force/moment equilibrium analyses. Orifice flow and two-dimensional (2D) shallow water equations (SWE) are solved to simulate dam break flows at different breaching stages. Erosion rates of different soils with different construction compaction efforts are calculated using corresponding erosion formulae. The dam's real shape, soil properties, and surrounding area are programmed. Large outer 2D-SWE grids are used to control upstream and downstream hydraulic conditions and control the boundary conditions of orifice flow, and inner 2D-SWE flow is used to scour soil and perform force/moment equilibrium analyses. This model is validated using the European Commission IMPACT (Investigation of Extreme Flood Processes and Uncertainty) Test #5 in Norway, Teton Dam failure in Idaho, USA, and Quail Creek Dike failure in Utah, USA. All calculated peak outflows are within 10% errors of observed values. Simulation results show that, for a V-shaped dam like Teton Dam, a piping breach location at the abutment tends to result in a smaller peak breach outflow than the piping breach location at the dam's center; and if Teton Dam had broken from its center for internal erosion, a peak outflow of 117 851 m3/s, which is 81% larger than the peak outflow of 65 120 m3/s released from its right abutment, would have been released from Teton Dam. A lower piping inlet elevation tends to cause a faster/earlier piping breach than a higher piping inlet elevation.

Abstract:

To restore dam-blocked natural fish migratory passages, a growing number of artificial fishways have been built in water conservancy and hydropower projects in China. The Angu hydropower station involved diverse important fish habitats in the lower reaches of the Daduhe River in Southwest China. Therefore, a vertical slot fishway (VSF) and a nature-like fishway (NLF) were built near the backwater area of the reservoir to connect the upstream and downstream habitats. Hydrodynamic and aquatic ecological surveys were conducted after the completion of the project to estimate the fish passing effect of the two fishways. The results indicated that both fishways were in effective operation and could maintain the desired hydrodynamic conditions and be used by several local fish species. During the survey, 149 fish from 15 species and 111 fish from 17 species were captured by the traps in the VSF and NLF, respectively, while 1 263 fish from 27 species were found in the downstream area. Some species captured in the VSF were not found in the NLF, and vice versa, which implied the different preferences of fish. Meanwhile, 3 789 signals including 2 099 upward ones and 1 690 downward ones were monitored with an ultrasonic fish detector at the inlet of the VSF. These findings revealed the characteristics of fish species observed in and near the fishways and provided valuable insights into the different fish passing capabilities of VSF and NLF.

Abstract:

Submerged vegetation commonly grows and plays a vital role in aquatic ecosystems, but it is also regarded as a barrier to the passing flow. Numerical simulations of flow through and over submerged vegetation were carried out to investigate the effect of vegetation density on flow field. Numerical simulations were computationally set up to replicate flume experiments, in which vegetation was mimicked with flexible plastic strips. The fluid–structure interaction between flow and flexible vegetation was solved by coupling the two modules of the COMSOL packages. Two cases with different vegetation densities were simulated, and the results were successfully validated against the experimental data. The contours of the simulated time-averaged streamwise velocity and Reynolds stress were extracted to highlight the differences in mean and turbulent flow statistics. The turbulence intensity was found to be more sensitive to vegetation density than the time-averaged velocity. The developing length increased with the spacing between plants. The snapshots of the bending vegetation under instantaneous velocity and vorticity revealed that flexible vegetation responded to the effects of eddies in the shear layer by swaying periodically. The first two rows of vegetation suffered stronger approaching flow and were prone to more streamlined postures. In addition, the origin of tip vortices was investigated via the distribution of vorticity. The results reveal the variation of flow properties with bending submerged vegetation and provide useful reference for optimization of restoration projects.